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1

ChemInform Abstract: Catalytic Generation of Cesium Acetylide by CsF: Synthesis of 1,3-Benzothiazines from Cyclic Sulfenamides.

Cedric Spitz, Jean-Francois Lohier, Vincent Reboul, Patrick Metzner

Journal:

Year:

2009

File:

PDF, 30 KB

2009

2

Direct synthesis of sulfines by oxidation of enethiolizable thioketones

Anne Marie Le Nocher, Patrick Metzner

Journal:

Tetrahedron Letters

Year:

1991

Language:

english

File:

PDF, 216 KB

english, 1991

3

Catalytic Generation of Cesium Acetylide by CsF: Synthesis of 1,3-Benzothiazines from Cyclic Sulfenamides

Spitz, Cédric, Lohier, Jean-François, Reboul, Vincent, Metzner, Patrick

Journal:

Organic Letters

Year:

2009

Language:

english

File:

PDF, 767 KB

english, 2009

4

Sulfur Reagents in Organic Synthesis || Organosulfur Compounds as Intermediates in Organic Synthesis

Metzner, Patrick

Year:

1994

Language:

english

File:

PDF, 3.32 MB

english, 1994

5

Diastereoselective Formation of Dithioacetal Oxides from Aliphatic Sulfines under Thermodynamic Control

Florence Corbin, Carole Alayrac, Patrick Metzner

Journal:

European Journal of Organic Chemistry

Year:

1999

Language:

english

File:

PDF, 357 KB

english, 1999

6

Benzylic Metallation of Thiobenzamides and Thionaphthamides

David Ach, Vincent Reboul, Patrick Metzner

Journal:

European Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 329 KB

english, 2002

7

First Use of Axially Chiral Thioamides for the Stereocontrol of C−C Bond Formation

Shubhada Dantale, Vincent Reboul, Patrick Metzner, Christian Philouze

Journal:

Chemistry - A European Journal

Year:

2002

Language:

english

File:

PDF, 207 KB

english, 2002

8

Die erste durch eine Sulfinylgruppe stereochemisch kontrollierte Claisen-Umlagerung – Synthese von α-Sulfinyldithioestern

Dr. Carole Alayrac, Christophe Fromont, Dr. Patrick Metzner, Dr. Nguyen Trong Anh

Journal:

Angewandte Chemie

Year:

1997

Language:

german

File:

PDF, 413 KB

german, 1997

9

First Examples of a Claisen Rearrangement Stereocontrolled by a Sulfinyl Group: Synthesis of Novel α-Sulfinyl Dithioesters

Dr. Carole Alayrac, Christophe Fromont, Dr. Patrick Metzner, Dr. Nguyen Trong Anh

Journal:

Angewandte Chemie International Edition

Year:

1997

Language:

english

File:

PDF, 564 KB

english, 1997

10

ChemInform Abstract: Oxidation of Dithiocarbamates and Synthesis of a Stable Sulfine.

David Chevrie, Patrick Metzner

Journal:

Year:

1999

File:

PDF, 27 KB

1999

11

ChemInform Abstract: Synthesis of Substituted 2-Cyclopenten-1-ones from Oxodithioesters via a Domino Process.

Florence Corbin, Carole Alayrac, Patrick Metzner

Journal:

Year:

1999

File:

PDF, 31 KB

1999

12

ChemInform Abstract: Synthesis of Racemic and Enantiopure 2-Alkylsulfinyl Dithioacetates and Thioacetamides.

Carole Alayrac, Stephanie Nowaczyk, Margareth Lemarie, Patrick Metzner

Journal:

Year:

1999

File:

PDF, 32 KB

1999

13

ChemInform Abstract: Asymmetric Synthesis of Epoxides from Aldehydes Mediated by (+)-(2R,5R)-2,5-Dimethylthiolane.

Karine Julienne, Patrick Metzner, Vivien Henryon

Journal:

Year:

1999

File:

PDF, 30 KB

1999

14

ChemInform Abstract: Diastereoselective Formation of Dithioacetal Oxides from Aliphatic Sulfines under Thermodynamic Control.

Florence Corbin, Carole Alayrac, Patrick Metzner

Journal:

Year:

2000

Language:

english

File:

PDF, 35 KB

english, 2000

15

ChemInform Abstract: Thiocarbonyl Compounds as Specific Tools for Organic Synthesis

Patrick Metzner

Journal:

Year:

2000

File:

PDF, 24 KB

2000

16

ChemInform Abstract: A New Example of Dynamic Kinetic Resolution: Aminolysis of α-Sulfinyl γ-Unsaturated Dithioesters.

Carole Alayrac, Patrick Metzner

Journal:

Year:

2000

File:

PDF, 31 KB

2000

17

ChemInform Abstract: Asymmetric Synthesis Mediated by Chiral Sulfur Compounds

Patrick Metzner, Carole Alayrac, Karine Julienne, Stephanie Nowaczyk

Journal:

Year:

2000

File:

PDF, 24 KB

2000

18

ChemInform Abstract: A Catalytic Cycle for the Asymmetric Synthesis of Epoxides Using Sulfur Ylides.

Jacques Zanardi, Catherine Leriverend, Dimitri Aubert, Karine Julienne, Patrick Metzner

Journal:

Year:

2001

Language:

english

File:

PDF, 32 KB

english, 2001

19

ChemInform Abstract: First Chiral Selenium Ylides Used for Asymmetric Conversion of Aldehydes into Epoxides.

Hiroya Takada, Patrick Metzner, Christian Philouze

Journal:

Year:

2002

File:

PDF, 28 KB

2002

20

ChemInform Abstract: Asymmetric Thio-Claisen Rearrangement Induced by an Enantiopure Alkylsulfinyl Group. Unusual Preference for a Boat Transition State in the Acyclic Series.

Stephanie Nowaczyk, Carole Alayrac, Vincent Reboul, Patrick Metzner, Marie-Therese Averbuch-Pouchot

Journal:

Year:

2002

File:

PDF, 39 KB

2002

21

ChemInform Abstract: First Use of Axially Chiral Thioamides for the Stereocontrol of C—C Bond Formation.

Shubhada Dantale, Vincent Reboul, Patrick Metzner, Christian Philouze

Journal:

Year:

2002

File:

PDF, 30 KB

2002

22

Benzylic Metalation of Thiobenzamides and Thionaphthamides.

David Ach, Vincent Reboul, Patrick Metzner

Journal:

Year:

2002

File:

PDF, 34 KB

2002

23

Highly Stereoselective C-Allylation of an Enantiopure α-Sulfinyl Thioacetamide.

Stephanie Nowaczyk, Carole Alayrac, Patrick Metzner, Marie-Therese Averbuch-Pouchot

Journal:

Year:

2003

File:

PDF, 163 KB

2003

24

First Enantioselective Synthesis of Vinyl Oxiranes from Aldehydes and Ylides Generated from Allyl Halides and Chiral Sulfides.

Jacques Zanardi, David Lamazure, Stephanie Miniere, Vincent Reboul, Patrick Metzner

Journal:

Year:

2003

File:

PDF, 224 KB

2003

25

Atroposelectivity of Reactions of Benzylic Metalated Thiobenzamides and Thionaphthamides.

David Ach, Vincent Reboul, Patrick Metzner

Journal:

Year:

2003

File:

PDF, 125 KB

2003

26

First Epoxidation Reaction of Carbonyl Compounds via Ferrocenyl Sulfur Ylides.

Stephanie Miniere, Vincent Reboul, Ramon Gomez Arrayas, Patrick Metzner, Juan Carlos Carretero

Journal:

Year:

2004

File:

PDF, 176 KB

2004

27

Syntheses of Sulfoxide Derivatives in the Benzodiazine Series. Diazines. Part 37.

Nicolas Le Fur, Ljubica Mojovic, Alain Turck, Nelly Ple, Guy Queguiner, Vincent Reboul, Stephane Perrio, Patrick Metzner

Journal:

Year:

2004

File:

PDF, 33 KB

2004

28

Syntheses of Sulfoxide Derivatives in the Benzodiazine Series. Diazines. Part 37.

Nicolas Le Fur, Ljubica Mojovic, Alain Turck, Nelly Ple, Guy Queguiner, Vincent Reboul, Stephane Perrio, Patrick Metzner

Journal:

Year:

2004

File:

PDF, 23 KB

2004

29

Catalytic Ferrocenyl Sulfides for the Asymmetric Transformation of Aldehydes into Epoxides.

Stephanie Miniere, Vincent Reboul, Patrick Metzner, Mariafrancesca Fochi, Bianca Flavia Bonini

Journal:

Year:

2005

File:

PDF, 20 KB

2005

30

Direct Utilization of Naturally Occurring Sulfides for the Asymmetric Epoxidation of Aldehydes Mediated by Catalytic Ylides.

Jacques Zanardi, Vincent Reboul, Patrick Metzner

Journal:

Year:

2005

File:

PDF, 17 KB

2005

31

Chalcogen Chiral Ylides for the Catalytic Asymmetric Epoxidation of Aldehydes: From Sulfur to Selenium and Tellurium

Jean-Francois Briere, Hiroya Takada, Patrick Metzner

Journal:

Year:

2005

File:

PDF, 8 KB

2005

32

Remarkably Mild and Simple Preparation of Sulfenate Anions from β-Sulfinylesters: A New Route to Enantioenriched Sulfoxides.

Caroline Caupene, Cedric Boudou, Stephane Perrio, Patrick Metzner

Journal:

Year:

2005

File:

PDF, 22 KB

2005

33

Developments of Asymmetric Synthesis Mediated by Chiral Sulfur Reagents

Virginie Blot, Jean-Francois Briere, Marion Davoust, Stephanie Miniere, Vincent Reboul, Patrick Metzner

Journal:

Year:

2005

File:

PDF, 8 KB

2005

34

ChemInform Abstract: Synthesis and Use of Chiral Sulfur Ylides

Jean-Francois Briere, Patrick Metzner

Journal:

Year:

2009

File:

PDF, 11 KB

2009

35

ChemInform Abstract: Fluoride Ion and Phosphines as Nucleophilic Catalysts: Synthesis of 1,4-Benzothiazepines from Cyclic Sulfenamides.

Cedric Spitz, Jean-Francois Lohier, Jana Sopkova-de Oliveira Santos, Vincent Reboul, Patrick Metzner

Journal:

Year:

2009

File:

PDF, 33 KB

2009

36

ChemInform Abstract: Cyclic Sulfenamide: Versatile Template for the Synthesis of 1,4-Benzothiazepines.

Cedric Spitz, Vincent Rebou, Patrick Metzner

Journal:

Year:

2012

File:

PDF, 35 KB

2012

37

Atroposelectivity of Reactions of Benzylic Metalated Thiobenzamides and Thionaphthamides

David Ach, Vincent Reboul, Patrick Metzner

Journal:

European Journal of Organic Chemistry

Year:

2003

Language:

english

File:

PDF, 205 KB

english, 2003

38

Studies Directed towards the Enantioselective Synthesis of Ethisolide and Isoavenaciolide

Virginie Blot, Vincent Reboul, Patrick Metzner

Journal:

European Journal of Organic Chemistry

Year:

2006

Language:

english

File:

PDF, 137 KB

english, 2006

39

Exclusive thiophilic addition of organo-magnesium compounds to a thioketone

Patrick Metzner, Jean Vialle, Alain Vibet

Journal:

Tetrahedron Letters

Year:

1976

Language:

english

File:

PDF, 147 KB

english, 1976

40

Dithioester as hetero-dienophiles in diels-alder cycloaddition - synthesis of 6-alkylthio-5,6-dihyro-2H-thiopyrans.

Pierre Beslin, Patrick Metzner

Journal:

Tetrahedron Letters

Year:

1980

Language:

english

File:

PDF, 133 KB

english, 1980

41

The first synthesis of aliphatic sulfines from thiono-esters

Margareth Lemarié, Thi-Nhàn Pham, Patrick Metzner

Journal:

Tetrahedron Letters

Year:

1991

Language:

english

File:

PDF, 147 KB

english, 1991

42

Thiophilic addition of organolithiums to aliphatic sulfines

Carole Alayrac, Francesca Cerreta, Isabelle Chapron, Florence Corbin, Patrick Metzner

Journal:

Tetrahedron Letters

Year:

1996

Language:

english

File:

PDF, 222 KB

english, 1996

43

Catalytic ferrocenyl sulfides for the asymmetric transformation of aldehydes into epoxides

Stéphanie Minière, Vincent Reboul, Patrick Metzner, Mariafrancesca Fochi, Bianca Flavia Bonini

Journal:

Tetrahedron: Asymmetry

Year:

2004

Language:

english

File:

PDF, 309 KB

english, 2004

44

Screening of amino sulfur ferrocenes as catalysts for the enantioselective addition of diethylzinc to benzaldehyde

Guillaume Grach, Vincent Reboul, Patrick Metzner

Journal:

Tetrahedron: Asymmetry

Year:

2008

Language:

english

File:

PDF, 291 KB

english, 2008

45

An efficient and rapid chalcogenide-Morita–Baylis–Hillman process promoted by TBDMSOTf and a thiolane

Jamjanam Srivardhana Rao, Jean-François Brière, Patrick Metzner, Deevi Basavaiah

Journal:

Tetrahedron Letters

Year:

2006

Language:

english

File:

PDF, 115 KB

english, 2006

46

Stéréospécificité de l'addition de Michael d'ènethiolates avec les énones acycliques

Kafui Kpegba, Patrick Metzner, Rosé Rakotonirina

Journal:

Year:

1989

File:

PDF, 1.37 MB

1989

47

Auto-protonation diastereoselective d' enolates issus de l'addition-1,4 d'nethiolates avec des enones

Sald Berrada, Stéphane Desert, Patrick Metzner

Journal:

Year:

1988

File:

PDF, 1.34 MB

1988

48

Access to diethylenic dithioesters by thio-claisen rearrangement : Further examples of reversibility of the claisen rearrangement

Patrick Metzner, Thi Nhan Pham, Jean Vialle

Journal:

Year:

1986

Language:

english

File:

PDF, 934 KB

english, 1986

49

Diastereoselectivity of the thio-Claisen rearrangement of acyclic precursors bearing a chiral centre adjacent to carbon 6

Stéphane Désert, Patrick Metzner

Journal:

Year:

1992

Language:

english

File:

PDF, 1.05 MB

english, 1992

50

Acyclic stereocontrol through the thio-Claisen rearrangement of precursors bearing a chiral centre adjacent to carbon 1

Stéphane Désert, Patrick Metzner, Mohamed Ramdani

Journal:

Year:

1992

Language:

english

File:

PDF, 997 KB

english, 1992

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